How-to
Storing slides and film negatives
Find out what your old negatives are made of, sleeve them in enclosures that passed the Photographic Activity Test, and keep any nitrate film apart from everything else.
Satisfy+ Editorial · Published July 30, 2026 · 3 min read · 1.5 hr to do

At a glance
- Handle
- Edges only, in lint-free gloves
- Sleeves
- Passed the Photographic Activity Test, never PVC or glassine
- A vinegar smell
- Acetate film breaking down
- Nitrate
- Common from about 1910 to 1950, flammable, kept apart
Film comes in three common bases. Polyester is stable. Cellulose nitrate and cellulose acetate, the "safety film" that replaced it, are not, and once they start to break down the damage can't be reversed. Nitrate gives off toxic fumes and becomes more dangerous as it deteriorates. Acetate gives off acetic acid, the vinegar syndrome, which damages film and papers stored near it. Knowing what you have comes first.
What you need
- Lint-free gloves, since oils and sweat damage the image
- Enclosures that passed the Photographic Activity Test (PAT)
- An archival box
Steps
- 1
Put on gloves
Hold negatives and slides by their edges, and never with bare hands.
2 min
- 2
Read the edge markings
Look along the film's border for printed words. "Nitrate" means cellulose nitrate, "Safety" means acetate, and "Estar" or "Cronar" means polyester. A copy negative can carry both "nitrate" and "safety", meaning an acetate copy of nitrate film. Some film has no marking at all.
20 min
- 3
Check for notches and damage
On Kodak film from before 1949, a V-shaped notch nearest the edge marks nitrate and a U-shaped one marks acetate. A sharp acid smell, stickiness or an amber tint points to nitrate breaking down. A vinegar smell, curling, shrinking or brittleness points to acetate.
10 min
- 4
Choose the enclosures
Use sleeves or envelopes that passed the PAT and meet the ANSI IT9.2 standard. Where test results aren't available, pick lignin-free, 100% rag paper that isn't strongly colored, especially not black. Skip glassine, and never use PVC, often sold as vinyl.
5 min
- 5
Rehouse the film
Slide each strip or slide into its own enclosure. In a paper envelope with a seam, face the image side away from the seam. Use paper rather than plastic for nitrate and early safety film, since plastic traps the gases they give off.
30 min
- 6
Label and box it
Note what's in each paper enclosure on its outside, since paper takes writing easily. Stand them in an archival box somewhere cool and dry.
8 min
Rehouse the old negatives and slides
- Check the negatives' edges for nitrate or safety markings
- Move the negatives into sleeves that passed the PAT
- Check the stored negatives for a vinegar smell
Plastic or paper
Clear plastic sleeves of polyester, polypropylene or polyethylene let you see the image without taking it out, which saves wear. They should be uncoated, with no plasticizers, and not matte or frosted, which can scratch. Plastic belongs only in a dry, steady room, since it can trap moisture and make the image stick to the sleeve. Paper is opaque and breathes, but you have to take the film out to look at it.
Nitrate film
Nitrate was most common from about 1910 to 1950, for still negatives and motion picture film. Paper photographs are never nitrate. Deteriorated nitrate is highly flammable, and its fumes irritate the lungs, eyes and skin. If you find it:
- Keep it away from heat, sparks and open flame.
- Store it apart from other photographs and papers, in paper enclosures, never in plastic.
- Don't put it in the trash.
- Ask an archivist or photograph conservator about copying the images and disposing of the film.
Cold storage
Cold storage slows the decay of film. A frost-free household upright freezer can work for a small collection, but the film needs vapor-proof packaging first, and every trip into the freezer to look for something shortens the film's life.
FAQ
How can I tell if my old negatives are nitrate?
Look for "nitrate" printed on the film's edge. Nitrate was most common from about 1910 to 1950. A sharp acid smell, stickiness or an amber tint can also point to it.
Why do my old negatives smell like vinegar?
Acetate safety film gives off acetic acid as it breaks down. Keep it apart from other photographs, since the fumes damage what's nearby.
What sleeves should I use for negatives?
Ones that passed the Photographic Activity Test. Avoid PVC, often sold as vinyl, and glassine.
Sources
Checked October 20, 2026
- National Park Service. Conserve O Gram 14/2: storage enclosures for photographic prints and negatives (1993)
- National Park Service. Conserve O Gram 14/9: identification of film-base photographic materials (1999)
- National Park Service. Conserve O Gram 14/8: caring for cellulose nitrate film (2004)
- National Park Service. Conserve O Gram 14/11: cold storage for photograph collections, using individual freezer units (2009)
- Owner
- Beginner
- Tenant
- DIY


